Bayern Munich striker Kane will lead his country out once more when Gareth Southgate's side open its campaign against Serbia on Monday (AEST).

Having fallen short in the delayed UEFA Euro 2020 final against Italy, as well as FIFA World Clup semi-final elimination to Croatia in 2018, Kane is without international glory, and his lack of club success is much discussed, too.

Kane acknowledged his own shortcomings as the England captain aims for national success in Germany.

"I love playing for my country," he said. "It means the world to me every time I step out onto the pitch wearing that shirt.

"To win a major tournament with England would be the pinnacle of anyone's career. That's the aim.

"For me personally, the trophies haven't quite happened yet, but it just makes me more determined and more hungry to go out there and do that.

"It starts with this summer, where we have a good opportunity. We have a lot of hard work in front of us, but that opportunity is there and I'm looking forward to making it happen."

Kane is England’s record goalscorer overall with 63 goals, and its most prolific player at major tournaments, having scored 12 goals at FIFA World Cups and European championships combined.

He scored or assisted in all seven of his starts in qualifying – eight goals and two assists – and heads into this tournament after a fine club season with Bayern.

The former Tottenham Hotspur forward scored 36 goals in 32 Bundesliga games for the most prolific debut campaign in the competition's history.

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Yet international success is all that matters over the next month for Kane.

"Every tournament brings different expectations," Kane added. "We've earned the right to be classed as one of the favourites.

"In past tournaments, we've done a lot of things well and done the country proud but, ultimately, we're here to win it and there'll be nothing better for us and the nation itself than if we do that."

As for his own success, individual achievements are far from Kane's priority.

"Back in 2018, the Golden Boot was an amazing achievement, but that's always a consequence of winning games and trying to win the European Championship, which is what we're trying to do," he said.

"If I win the Golden Boot along the way, fantastic as I'm helping my team.

"We have some great goalscorers in the team, players who are on form, who've had fantastic seasons, so now it's about taking that into a major tournament."