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Brazilian club Bahia defeated Uruguay's Boston River 1-0 to snatch the final Copa Libertadores group stage spot.
Carlos Alcaraz survived a second set scare before rallying to a 6-3 7-6 win over in-form Francisco Cerundolo.
The first major silverware of the season is up for grabs in the Carabao Cup final, with Wembley the stage as two of the world's in-form club teams battle it out for the title.